I have some jQuery that sends data to a AddComment.php page. The data is a user id (could be gotten through a session), an item id and a comment under text form.
In this case, should all data be sent through a POST? Are there cases where one might find a mix of GET and POST?
Go read RFC 2616.
There are very specific semantics associated with GET and POST which have a big impact on caching and on logging.
In the case of your example, the data to be added should be sent in a POST. Whether a reference to the item being commented on should be sent via POST or GET variable is debatable. (you can POST to a URL with a query string and any competent web language should be able to discriminate between the same variable name sent via both methods)
A more transparent example of when GET and POST should be mixed is when POSTing to a front-controller – here the same path is used by various different bits of functionality (web pages if you like). The specific bit of functionality being invoked is indicated by the query in a GET operation. If the selection criteria are moved into the POST then you have to cater for both scenarios within the front controller, and you lose resolution of the functionality in the log files.