
(source: googlepages.com)
In above image I want to mark Circle’s edge with red color
something like this

(source: googlepages.com)
I have no idea how should proceed, Any help/suggestions would be highly appreciated…
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Morphological filtering would work great as long as you are working with binary images like the one you provided. Dilate the image and then subtract the original.
alt text http://img29.imageshack.us/img29/1420/morphf.png
Here’s a MATLAB example: