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Here’s the MSDN page about Data deduplication API, and it seems there’s no API to check if a volume is deduped.
One way to do it is to check if there’s a folder named “Dedup” under “System Volume Information”, but I don’t think it is reliable for every case.
The list of deduped volumes can be obtained in powershell. See the following link about a third of the way down the page
http://windows-scripting.org/category/windows-2012/