I am using a pretty long StringFormat for my bound tooltip and am currenly trying to make it multiline in XAML.
While I was able to make literal ToolTip multiline using 
 for line breaks I am unable to get it to work with StringFormat.
I am trying to get following code to give me a tooltip with line break:
ToolTipService.Tooltip= {Binding Property,StringFormat='FORMAT WITH LINE BREAK {0}'}
Actually I got correct answer here:
official silverlight forums link
We can use

for line break.or :
Difference is pretty big.. This one works.