I have a worksheet with many rows/columns like so:

How can I only copy the unique values from this sheet to a blank one using a function?
I only need the row with first occurence, the rest do not matter.
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You can add a formula in the next column to indicate if the value already occurs in the cells above. See below:
Add this formula to all cells except the first row. Now you can filter for cells that do not contain “DUP” and copy-paste the filtered list to another sheet.