I have attached the image below of the menu which i am using for my site , Apart from IE , all the other browsers renders the correct output :

Even in IE9 the hover effect should be curvy but it comes up with rectangular effect .
Firefox , safari , and chrome works fine :

Css
header nav {
padding:7px 0 10px 0;
}
header nav ul {
float:right;
padding:2px 0 0 0;
}
header nav ul li {
float:left;
padding-left:4px;
}
header nav ul li a {
position:relative;
float:left;
font-size:14px;
color:#fff;
text-decoration:none;
font-family: 'ColaborateThinRegular';
text-transform:uppercase;
height:32px;
line-height:32px;
background-color:#181717;
padding:0 36px 0 10px;
border-radius:17px;
-moz-border-radius:17px;
-webkit-border-radius:17px;
}
header nav ul li a:hover,
header nav ul li a.current {
background-image: -moz-linear-gradient(top, #E53088, #E530C1); /* FF3.6 */
background-image: -webkit-gradient(linear,left bottom,left top,color-stop(0, #E53088),color-stop(1, #E530C1)); /* Saf4+, Chrome */
filter: progid:DXImageTransform.Microsoft.gradient(startColorstr='#E53088', endColorstr='#E530C1'); /* IE6,IE7 */
-ms-filter: "progid:DXImageTransform.Microsoft.gradient(startColorstr='#E53088', endColorstr='#E530C1')"; /* IE8 */
border-radius:17px;
-moz-border-radius:17px;
-webkit-border-radius:17px;
}
I am looking for the same behaviour like firefox, chrome and safari
The gradient filter in Internet Explorer doesn’t get clipped by the
border-radiusin Internet Explorer 9. The only solution I can think of involves having an inner<div>element with the gradient applied:Apply the
border-radiusto the<li>element and the gradient to<div class="gradient">. This should give the correct result.The only other option, as Salman A mentioned, is CSS3 PIE, which work around this problem for you and implement
border-radiusin older versions of IE. I’m using this in a couple of projects and it works very well.