I know, we are in 2011 and not in 1998. But a customer asked to make a web site in ASP vs. an Access DB. I’ve read many bad things but I would really like what are the limitations of Access (after 2003) and the real reasons why not to use it (are their limitations on max concurrent user access? Is it unscalable? Breakable? etc.).
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You can use Access 2010 to build websites with Sharepoint: http://www.youtube.com/watch?v=AU4mH0jPntI
Otherwise, it is unlikely to be a good idea, unless you are thinking of a private website, it which case it is do-able, with care, but still, not necessarily a good idea.
This document contains an interesting table of limitations etc