I want to exclude one of the skill-types that are called in the code below, is this possible?
<ul>
<li><a href="#" class="all active"><?php _e('All', 'framework'); ?></a><span>/</span></li>
<?php
wp_list_categories(array(
'title_li' => '',
'taxonomy' => 'skill-type',
'walker' => new Portfolio_Walker(),
'show_option_none' => ''
));
?>
</ul>
Have you checked the Documentation?
You can use the exclude parameter to define a comma-separated list of term IDs: