I’m creating a gridview dynamically based on number of users selected but want to add detail when a specific cell of the gridview is hovered over/clicked. For instance if the logons of User1 was hovered over/clicked it would create a popup or another window with the details of logon times pulled from the database. TIA

There are plenty of jQuery plug-ins that will do want you want client-side like QTip or jQuery UI’s dialog. Where you can combine them with an Ajax call to pull whatever data you want.
EDIT: For information to send back client-side, you could use a hidden input to hold the information you need:
Then access it with jQuery (sample):
EDIT 2: If you’re dynamically generating the grid server-side, you can add an HtmlInputHidden to the grid cell wherever you’re creating your cells: