I’m Trying to design the Conversation View for a chat Application in windows 8 Metro App. I’m new to xaml designs, how to set the Conversation view like the image below,

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Although at first time it seems this layout can be fit into Grid with three columns, I’m sure you would need scrolling at some point. So, you can just use
Canvas, which allows free-floating controls. Place them withCanvas.LeftandCanvas.Topattached properties.Update: an illustration of what I mean:
Let’s pretend that red borders are user pics (put
Imageinside) and gray borders are messages (putRichTextBlockinside.) Canvas allows you to shift those blocks freely.