Is there any way that I can embed a .exe file in a .pdf, .doc, .xls, or .ppt file in such a way that upon opening the containing file, the document processor will run the .exe automatically without the user intentionally executing it?
Is there any way that I can embed a .exe file in a .pdf
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Yes, this is totally possible and pretty easy to accomplish – so long as you have an active exploit in the PDF viewer. Check out one of the many Adobe Acrobat Exploits in the Metasploit framework. Next you can use a download+exec shellcode to download and execute your payload, err I mean ".exe".