Is there way to customize TabBar like this?
We use iOS5.

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Yes this isn’t actually to difficult to do.
1) Subclass UITTabBarController
2) Run a method to hide all UITabBar class elements like below
3) Draw your own elements onto self ([self.view addSubview:CustomButton])
EDIT
As a further update to explain how your image example is done. You have 4 elements:
1) Background image
2) Left button
3) Middle button
4) Right button
So UIImageView and UIButton with [UIButton buttonWithType:UIButtonTypeCustom] are all you need for this magic to happen.