Question

Kindly see the Table Structure , Query and the Result.

MeetingRoom

   ID | Area | RoomNo    Capacity   distances 
   --- ----- --------- ---------- ----------
   1   1     R1         10        10        
   2   1     R3         24        4         
   3   8     R4         24        4         
   4   1     R5         10        10     

ReservationTable

ReservationID RoomID      DateTimeStart           DateTimeEnd             
------------- ----------- ----------------------- ----------------------- 
1             1           2013-10-10 17:00:00.000 2013-10-10 19:00:00.000 

Query

 Declare @Start Datetime
 Declare @End Datetime

 set @Start='2013-10-10 13:00:00.000'
 set @End='2013-10-10 14:00:00.000'

 select 
     MeetingRoom.ID 
 from 
    MeetingRoom 
    left Join ResReservationTable Res on Res.RoomID = MeetingRoom.ID
 Where 
   Res.DateTimeStart != @Start and Res.DateTimeEnd != @End
   and (Res.DateTimeStart Not Between @Start and @End) 
   and (Res.DateTimeEnd Not Between @Start and @End)

This Query is Returning only one record as it should return 4 Records

Answer 1

If you use LEFT OUTER JOIN and in WHERE clause set condition to right-hand table rather than IS NULL in result you have INNER JOIN.

I think this is what you want.

Declare @Start Datetime
Declare @End Datetime

set @Start='2013-10-10 13:00:00.000'
set @End='2013-10-10 14:00:00.000'

select 
     MeetingRoom.ID 
from 
    MeetingRoom 
    left Join ResReservationTable Res on Res.RoomID = MeetingRoom.ID
Where
  (
   Res.DateTimeStart != @Start and Res.DateTimeEnd != @End
   and (Res.DateTimeStart Not Between @Start and @End) 
   and (Res.DateTimeEnd Not Between @Start and @End)
  )
  OR Res.ReservationID IS NULL

I think you must rephrase your WHERE condition. If you want room which fully free (i.e. intervals not intersect) you can use this:

WHERE
   Res.DateTimeStart > @End
   OR Res.DateTimeEnd < @Start
   OR Res.ReservationID IS NULL