The problem is the ServiceDocument as the xmlns attribute on it.
—Preassigned XML
System.Xml.XmlDocument xmlDoc = new XmlDocument();
xmlDoc.LoadXml("<?xml version=\"1.0\" encoding=\"utf-8\"?>
<ServiceDocument
xmlns:i=\"http://www.w3.org/2001/XMLSchema-instance\"
xmlns=\"http://schemas.microsoft.com/ado/2007/08/dataservices\"
>
<BaseUri>
http://xxxx.xxxxx.net/xxx.1/
</BaseUri>
<ProfilesLink>
http://adf.apis.dds.net/af.1/
</ProfilesLink>
<SignedInUser>
<Cid>
4433sfsdfgd
</Cid>
<Uri>
http://fd.apis.afdafd.net/V4.1/cid-xxxxx/adad
</Uri>
</SignedInUser>
<StatusMessageLink>
http://psm.adfa.afd.net/dfa.1/
</StatusMessageLink>
</ServiceDocument>"
);
// Response.Write(xmlDoc.InnerXml);
–//PARSE XML problem is below**
Response.Write(xmlDoc.SelectSingleNode("/ServiceDocument/BaseUri").InnerXml);
You need to assign short aliases to the namespaces using the XMLNamespaceManager.
See this page for an example.
So, to solve your problem: