There was a site, Web Design From Scratch (archived link, no longer has the following behavior), where the browser would render the fonts at first, and then quickly the header text flickered and then it became an image.
Does anyone know what technique was being used here?
They are using Cufón:
The above is applying the library to all h1 elements, I would imagine.
Another popular technique to achieve this is sIFR, however that requires Flash. The Cufón website says: