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which protocol is used (other than NDEF protocol) for communication between Mifare classic 1k and nfc enabled mobile, when we raed or write indvisual blocks.
NDEF is not a communication protocol, but the message content description:
“…The NDEF specification defines a message encapsulation format to
exchange information… NDEF is a lightweight, binary message format that can be used to encapsulate one or more application-defined payloads of arbitrary type and size into a single message construct. Each payload is described by a type, a length, and an optional identifier.
Type identifiers may be URIs, MIME media types, or NFC-specific types…“
The protocol to read/write Mifare sectors is a proprietary see e.g. here: http://www.nxp.com/documents/data_sheet/MF1S503x.pdf
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