Within a regex seems that it is the same:
if(preg_match('/\x{61}/',"a",$m)) //Same as just \x61
print_r($m);
But if you make echo both apart.
echo "\x61";//Display a
echo "\x{61}";//Display \x{61}
Note: Not confuse with the '/\x{0000}/u'
I don’t see info about that and I’m not sure which to use.
pcre has its own escape rules, which are different from those in php. From http://www.pcre.org/pcre.txt